Elemental bromine is so reactive that it does not occur

Commercially, the element is readily extracted from brine evaporation ponds, mainly in the United States and Israel. The mass of bromine in the ocean is about one-thirtieth that of chlorine.

Bromine is a naturally occurring element that is liquid at room temperature. It is reddish brown in color, has a bleach-like odor and is soluble in water.

Bromine is a chemical element with the symbol Br and atomic number 35. It is a volatile reddish-brown liquid at room temperature that evaporates readily to form a similarly colored vapor. Its properties are between chlorine and iodine. Independently isolated by two chemists, Carl Jacob Löwig (1825) and Antoine Jérôme Balard (1826), its name is derived from the ancient Greek βρῶμος (bromos), meaning "foul smell", referring to its pungent pungent odor.

 

Elemental bromine is so reactive that it does not occur in nature as a natural element, but rather as a colorless soluble crystalline mineral halide salt, similar to table salt. In fact, bromine and all halogens are so reactive that they form bonds in pairs -- not single atoms. Although it is fairly rare in the Earth's crust, the high solubility of the bromide ion (Br−) causes it to accumulate in the oceans. Commercially, the element is readily extracted from brine evaporation ponds, mainly in the United States and Israel. The mass of bromine in the ocean is about one-thirtieth that of chlorine.

A large amount of bromine salt reacts toxically with soluble bromide ions, causing bromine poisoning. However, a clear biological role for bromide ions and hypobromous acid has recently been elucidated, and bromine now appears to be an essential trace element for humans. The role of bioorganobromine compounds in marine organisms such as seaweed has long been known. As a drug, the simple bromide ion (Br−) has a depressant effect on the central nervous system, and bromide salts were once the main medical sedatives before being replaced by short-acting drugs. They retain a niche use as antiepileptic drugs.

Bromine was independently discovered by two chemists, Carl Jacob Löwig[6] and Antoine Balard[7][8] in 1825 and 1826 respectively. [9]

 

Löwig isolated bromine in 1825 from mineral water in his hometown of Bad Kreuznach. Löwig used a solution of mineral salts saturated with chlorine and extracted the bromine with ether. Evaporation of ether left a brown liquid. Using this liquid as a sample for his work, he applied for a position in the laboratory of Leopold Gmelin in Heidelberg. The publication of the results was delayed, and Ballard published his results first. [10]

 

Under standard conditions of temperature and pressure, it is a liquid; the only other element that is liquid under these conditions is mercury. At high temperature, organic bromine compounds are easily decomposed to generate free bromine atoms, a process that can prevent free radical chemical chain reactions. This effect makes organobromine compounds useful as flame retardants, for which more than half of the bromine produced worldwide is used annually. The same property causes ultraviolet sunlight to decompose volatile organic bromine compounds in the atmosphere, producing free bromine atoms that contribute to ozone depletion. As a result, many organobrominated compounds – such as the pesticide methyl bromide – are no longer used. Brominated compounds are still used in drilling fluids, photographic film, and as intermediates in the manufacture of organic chemicals.


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